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Creators/Authors contains: "Trammel, Grace L."

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  1. ; ; ; ; (, Journal of the American Chemical Society)
    null (Ed.)
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  2. ; ; ; ; ; (, Journal of the American Chemical Society)
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  3. ; ; ; ; ; (, Angewandte Chemie International Edition)
    Abstract Two catalytic systems have been developed for the arylboration of endocyclic enecarbamates to deliver synthetically versatile borylated saturated N‐heterocycles in good regio‐ and diastereoselectivities. A Cu/Pd dual catalytic reaction enables the synthesis of borylated, α‐arylated azetidines, while a Ni‐catalysed arylboration reaction efficiently functionalizes 5‐, 6‐, and 7‐membered enecarbamates. In the case of the Cu/Pd‐system, a remarkable additive effect was identified that allowed for broader scope. The products are synthetically useful, as demonstrated by manipulations of the boronic ester to access biologically active compounds. 
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